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A novel C[dbnd]N bond forming strategy based on oxo/imido heterometathesis between N-sulfinylamines and ketones, catalyzed by a well-defined silica-supported Ti imido complex, was applied to prepare a series of hardly accessible 1,1?-diacetylferrocene ketimines.
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Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion