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A new class of phosphorus compounds containing a ferrocenyl unit are obtained from vinylferrocene and phosphono-substituted aromatic halides by using palladium-catalyzed Heck-type reactions. The crystal structure of compound 3a confirms the trans planar geometry of the pi-conjugated system. The electrochemistry and electronic absorption spectra of phosphorus esters 3a,b and acids 4a,b are investigated.
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Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion