Synthetic Route of 1273-94-5, Academic researchers, R&D teams, teachers, students, policy makers and the media all rely on us to share knowledge that is reliable, accurate and cutting-edge. In a document type is Article, and a compound is mentioned, 1273-94-5, name is 1,1′-Diacetylferrocene, introducing its new discovery.
X-ray analysis reveals that both thiosemicarbazone groups of the title compound, [Fe(C8H10N3S)2]·H 2O, are in the keto tautomeric form and that the configuration of the azomethine C=N double bond is E. The two cyclopentadienyl rings are parallel and nearly eclipsed. The crystal structure is stabilized by extensive intra- and intermolecular hydrogen bonding involving the water molecule and the thiosemicarbazone moieties.
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Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion