As a society publisher, everything we do is to support the scientific community – so you can trust us to always act in your best interests, Electric Literature of 1273-86-5, and get your work the international recognition that it deserves. Introducing a new discovery about 1273-86-5, Name is Ferrocenemethanol
Ferrocenyltrithiocarbonates (I) are readily obtained by treating alpha-ferrocenylcarbinols (II) successively with sodium hydride, carbon disulfide and alkyl halide.Formation of I occurs by intramolecular nucleophilic displacement of oxygen by sulfur with retention of configuration.This is supported by the nature of the other products formed and by the X-ray structure determination of an optically active compound I, which was refined to R = 0.038.The title compound of R configuration was obtained from (R)-ferrocenylmethylmethanol.
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Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion