Some scientific research about 16009-13-5

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Related Products of 16009-13-5, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 16009-13-5, Name is Hemin, molecular weight is 651.94. In an Article,once mentioned of 16009-13-5

Concentration dependent chemical shifts, line widths, and spin-lattice relaxation rates of dicyanohemin at pH 9 can be attributed to intermolecular paramagnetic dipolar relaxation processes within a stereospecific dimer.The r-6 dependence of the relaxation rates permits determination of the dimer structure which consists of overlap of presumably parallel porphyrin planes (ca. 5-Angstroem separation) with the 2-vinyl and 3-methyl groups of each porhyrine in contact with the aromatic ?-system of the other porphyrin and the propionate side sections extending into the solvent.This structure points to the important role of hydrophobic interactions in stabilizing the dimer.At higher pH values, particularly at higher temperatures (> 25 deg C), the dicyanohemin undergoes displacement of cyanide by one or more hydroxide ions.

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Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion