In heterogeneous catalysis, the catalyst is in a different phase from the reactants. Computed Properties of C12H10FeO2, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 1271-48-3, name is 1,1′-Ferrocenedicarboxaldehyde. In an article£¬Which mentioned a new discovery about 1271-48-3
Self-assembly via (N?I) non-covalent bonds between 1,4-diiodo-tetrafluoro-benzene and a tetra-imino ferrocenophane
The tetra-imino ferrocenophane (1) was cocrystallized with 1,4-diiodo-tetrafluoro-benzene (TFDIB). In the resulting compound 2, two of the four ferrocenophane nitrogens show interactions with the iodine atoms of TFDIB leading to a polymeric structure with extended linear alternating electron donor (1) and acceptor (TFDIB) molecule chains. For the first time, imino nitrogens are involved in this type of halogen bonding. The N?I non-covalent bonds (N?I distances 2.879(5) and 2.896(5)A; N?I-C angles 171.1(2) and 178.1(2)) are the directing interactions responsible for the observed self-assembly. The ferrocene fragments of the macrocycle are in an almost perpendicular conformation. Moessbauer spectroscopy indicates the sole presence of low spin iron (II). The temperature dependence of the magnetic susceptibility is corresponding to a quasi-diamagnetic compound.
Self-assembly via (N?I) non-covalent bonds between 1,4-diiodo-tetrafluoro-benzene and a tetra-imino ferrocenophane
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 1271-48-3, help many people in the next few years.Computed Properties of C12H10FeO2
Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion