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A series of ferrocenyl derivatives (1, 2, 3 and 4) containing phenol group, chemosensors for anions, have been synthesized and optimized. Their binding ability for various anions (F-, Cl-, Br-, I-, AcO- and H2PO4-) were evaluated by theoretical investigation, UV-Vis, 1H NMR titration and cyclic voltammetry experiments and these chemosensors showed strong binding ability for oxy-anions. Theoretical investigation analysis revealed the substituent was different, the space structure was different. And the intramolecular hydrogen bond existed between -OH and other atoms in the structure of these compounds. UV-Vis titrations indicated the anion binding abilities could be tuned by electron push-pull properties of the substituents on the phenyl ortho or para position. Electrochemical titrations showed the addition of anions led to the weak of redox response and the oxidation peak potential moved to more positive potential gradually. In addition, these chemosensors were sensitive to the AcO- detection without the interference of other anions studied, as well as chemosensor 4 was sensitive to the H2PO4- detection.

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Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

 

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Reference of 1273-86-5, Healthcare careers for chemists are once again largely based in laboratories, although increasingly there is opportunity to work at the point of care, helping with patient investigation. 1273-86-5, Name is Ferrocenemethanol, molecular weight is 206.99. molecular formula is C11H3FeO. In an Article,once mentioned of 1273-86-5

We have developed a biosensing platform for lactate determination based on gold electrodes modified with diamond nanoparticles of 4 nm of nominal diameter, employing the enzyme lactate oxidase and (hydroxymethyl)ferrocene (HMF) as redox mediator in solution. This system displays a response towards lactate that is completely different to those typically observed for lactate biosensors based on other nanomaterials, such as graphene, carbon nanotubes, gold nanoparticles or even diamond nanoparticles of greater size. We have observed by cyclic voltammetry that, under certain experimental conditions, an irreversible wave (E0 = +0.15 V) appears concomitantly with the typical FeII/FeIII peaks (E0 = +0.30 V) of HMF. In this case, the biosensor response to lactate shows simultaneous electrocatalytic peaks at +0.15 V and +0.30 V, indicating the concurrence of different feedback mechanisms. The achievement of a biosensor response to lactate at +0.15 V is very convenient in order to avoid potential interferences. The developed biosensor presents a linear concentration range from 0.02 mM to 1.2 mM, a sensitivity of 6.1 muA mM-1, a detection limit of 5.3 muM and excellent stability. These analytical properties compare well with those obtained for other lactate-based biosensors that also include nanomaterials and employ HMF as redox mediator.

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Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

 

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The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing theoretical assessments of solvent structures and their interactions with reaction intermediates and transition states. Reference of 1273-86-5, You can get involved in discussing the latest developments in this exciting area about 1273-86-5

Chemical engineers ensure the efficiency and safety of chemical processes, adapt the chemical make-up of products to meet environmental or economic needs, and apply new technologies to improve existing processes. Reference of 1273-86-5. Catalysts allow a reaction to proceed via a pathway that has a lower activation energy than the uncatalyzed reaction. Introducing a new discovery about 1273-86-5, Name is Ferrocenemethanol

The present invention discloses a kind of […] triphenylphosphine link iridium hydrogen adduct, the compound has the following formula: , Wherein R is H, -CH 3, -OCH 3, -C 6 H 5 or-CHO, located in R the […] 3, 5, 6 or 8 position; the preparation of such compounds the steps of: fetching […] derivatives, iridous chloride and triphenylphosphine is added to the solvent, heating to reflux under the gas protection, is filtered to get after the reaction. The prepared […] triphenylphosphine link iridium hydrogen adduct is high activity of the catalyst, catalytic acetylenic and aryl benzalcohol reaction, the aryl ketone compounds. To […] derivatives triphenylphosphine link iridium hydrogen adduct a metal catalyst, the usage of catalyst is small, with cheap weak base, can be high-efficiency catalytic acetylenic and aryl benzalcohol reaction. The method has the mild reaction conditions, wide range of the reaction substrate, economic, high efficiency, and the like, has an important application value. (by machine translation)

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Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

 

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With the volume and accessibility of scientific research increasing across the world, it has never been more important to continue building the reputation for quality and ethical publishing we’ve spent the past two centuries establishing.In an article, 1293-65-8, molcular formula is C10Br2Fe, belongs to iron-catalyst compound, introducing its new discovery., Application of 1293-65-8

Diferrocenylketone (I) and <1.1>ferrocenophane-1,12-dione (II) have been obtained in 86percent and 13percent yields, respectively, via a simple route analogous to the Barbier synthesis involving N,N-disubstituted carbamylchlorides and the appropriate bromoferrocene derivatives.

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Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

 

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Application of 1293-65-8, Chemistry graduates have much scope to use their knowledge in a range of research sectors, including roles within chemical engineering, chemical and related industries, healthcare and more. 1293-65-8, Name is 1,1′-Dibromoferrocene, molecular weight is 335.76. In an Article,once mentioned of 1293-65-8

Non-aqueous redox flow batteries, because of larger operating voltage, have attracted considerable attention for high-density energy storage applications. However, the study of the anolyte is rather limited compared with the catholyte due to the labile properties of redox mediators at low potentials. Here, we report a new strategy that exploits high concentration organic lithium metal solution as a robust and energetic anolyte. The solution formed by dissolving metallic lithium with biphenyl (BP) in tetraethylene glycol dimethyl ether (TEGDME) presents a redox potential of 0.39 V versus Li/Li+, and a concentration up to 2 M. When coupled with a redox-targeted LiFePO4 catholyte system, the constructed redox flow lithium battery full cell delivers a cell voltage of 3.0 V and presents reasonably good cycling performance.

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Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

 

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Related Products of 1273-86-5, With the volume and accessibility of scientific research increasing across the world, it has never been more important to continue building the reputation for quality and ethical publishing we’ve spent the past two centuries establishing.In an article, 1273-86-5, molcular formula is C11H3FeO, belongs to iron-catalyst compound, introducing its new discovery.

The protection performance of self-assembled monolayers (SAMs) formed by 2-(Pyridin-2-yliminomethyl)-phenol (HL) on the surface of copper has been studied in situ with the scanning electrochemical microscope (SECM). The pitting dynamic processes were observed in sodium chloride solution without the presence of SAMs, but they tended to be inhibited by SAMs if the assembly time was long enough. During the scanning process, the self-assembled method decreases the interaction between the HL molecules and the SECM tip greatly.

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Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

 

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The direct high-yield synthesis without solvent and catalyst, under mild conditions, of eleven novel mono substituted ferrocenylmethyl ethers and amine derivatives from ferrocenemethanol and vicinal oxygenated alcohols and amines is here reported. The peculiar ability of these classes of non acidic compounds to favor the dehydrative nucleophilic substitution is attributed to the presence of vicinal oxygen atoms to the reactive group able to build a hydrogen bonding network with the reactant. The role of carbon dioxide and hexafluoroisopropanol was investigated to support the hypothesis that a template catalysis effect is occurring. The in vitro anti-fungal activity of some of these derivatives was tested on two plant fungi, Botrytis cinerea and Penicillium species, with moderate activity.

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Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

 

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This paper presents a complete test structure and characterisation system for the evaluation of nanoelectrode technology. It integrates microfabricated nanoelectrodes for electrochemical measurements, 3D printing and surface tensionconfined microfluidics. This system exploits the inherent analytical advantages of nanoelectrodes that enables their operation with small volume samples, which has potential applications for onwafer measurements.

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Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

 

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You could be based in a university, combining chemical research with teaching; in a pharmaceutical company, working on developing and trialing new drugs; category: iron-catalyst, or in a public-sector research center, helping to ensure national healthcare provision keeps pace with new discoveries.In a article, mentioned the application of 1273-86-5, Name is Ferrocenemethanol, molecular formula is C11H3FeO

In this work, we have studied the formation of complexes between flavonols, (quercetin, rutin, quercitrin, kaempferol, luteolin, tamarixetin) and flavanols ((+)-catechin, (-)-epicatechin), flavanonol, (+)-taxifolin, and Zn acetate in two hydro-organic media at neutral pH in the absence of oxygen. The complexation was first studied by cyclic voltammetry. Then preparative electrolysis have been attempted followed by coulometry, UV-Vis optical absorption and circular dicroism spectroscopies for characterizing the oxidized compounds. Spectroelectrochemistries monitored either in the UV-Vis or in the EPR spectrometers at room temperature have been also used and we have identified o-semi-quinone intermediates in some cases. Different behaviour vis-a-vis the complexation by Zn2+ according to the molecular structures of these different families of polyphenols have been found. Some of them are more easily oxidizible.

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Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

 

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Scanning electrochemical microscopy (SECM) can image graphene oxide (GO) flakes on insulating and conducting substrates. The contrast between GO and the substrate is controlled by the electrostatic interactions that are established between the charges of the molecular redox mediator and the charges present in the sheet/substrate. SECM also allows quantitative measurement-at the nano/microscale-of the charge transfer kinetics between single monolayer sheets and agent molecules. This journal is

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Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion