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Local electrochemical techniques such as scanning electrochemical microscopy, scanning vibrating electrode technique, local electrochemical impedance spectroscopy, scanning Kelvin probe technique, and scanning ion-selective electrode technique have gained significant attention in organic coating research. These techniques have enhanced our understanding of the fundamental processes of corrosion at defects and underneath coatings. Each of these techniques employ unique measurement strategy to provide important local information about coatings, their protective properties, defects, and failure mechanisms. In this brief review, the basic principles of these techniques and the nature of information that has been extracted from these techniques to study organic coatings are discussed.
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Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion