name: Ferrocenemethanol, Academic researchers, R&D teams, teachers, students, policy makers and the media all rely on us to share knowledge that is reliable, accurate and cutting-edge. In a document type is Article, and a compound is mentioned, 1273-86-5, name is Ferrocenemethanol, introducing its new discovery.
The complex Fc(CH=CH)2C?C-TMS (Fc = ferrocenyl) was obtained from Wittig olefination of FcCH2PPh3Br with TMS-C?CCH=CHCHO in THF. The conjugated monometallic diene can be desilylated to give Fc(CH=CH)2C?CH, which reacted with RuHCl(CO)(PPh3)3 to produce Fc(CH=CH)3RuCl(CO) (PPh3)2. Treatment of the latter complex with PMe 3, 4-phenylpyridine (PhPy), 2,6-(Ph2PCH2) 2C5H3N (PMP), and KTp (Tp = hydridotris(pyrazolyl)borate) gave Fc(CH=CH)3RuCl(CO)(PMe 3)3, Fc(CH=CH)3RuCl(CO)(PhPy)(PPh 3)2, Fc(CH= CH)3RuCl(CO)(PMP), and Fc(CH=CH)3RuTp(CO)(PPh3), respectively. The structures of Fc(CH=CH)2C?CH and Fc(CH=CH)3RuCl(CO)(PMe 3)3 have been confirmed by X-ray diffraction.
If you are interested in 1273-86-5, you can contact me at any time and look forward to more communication. The potential utility of systematic synthetic strategy will be applicable to efficient generations of chemical libraries of compounds to find ‘hit’ molecules. name: Ferrocenemethanol
Reference：
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion