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The diffusion rates of seven ferrocene derivatives have been estimated in polyelectrolyte PEG · LiClO4 by using non-steady-state chronoamperometry. The Dapp of ferrocene derivatives increases with temperature, and the dependency of Dapp on temperature obeys the Arrhenius equation. The Dapp of ferrocene derivatives decreases with increasing size of electroactive species. The DeltaDapp values of DT>Tm and DT
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Reference:
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion