Awesome Chemistry Experiments For 1273-86-5

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Synthetic Route of 1273-86-5, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.1273-86-5, Name is Ferrocenemethanol, molecular formula is C11H3FeO. In a Article£¬once mentioned of 1273-86-5

Ferrocenylalkylation of 2-mercaptobenzoxazoles

Regioselectivity of the HBF4-catalyzed ferrocenylalkylation of 2-mercaptobenzoxazole in two phase aqueous organic solvent mixture was studied. The reaction proceeds regioselectively at the heterocyclic nitrogen atom. Structures of the synthesized compounds were established by 2D NMR technique. Structure of 3-(1-ferrocenylbenzyl)benz[d]oxazol-2-thione was elucidated by X-ray diffraction.

Ferrocenylalkylation of 2-mercaptobenzoxazoles

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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

 

A new application about Ferrocenemethanol

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Electric Literature of 1273-86-5, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.1273-86-5, Name is Ferrocenemethanol, molecular formula is C11H3FeO. In a Article£¬once mentioned of 1273-86-5

Mild hydrolytic cleavage of alpha-ferrocenylalkyl-O-methyl ethers

The conversion of alpha-ferrocenylalkyl-O-methyl ethers into the corresponding alcohols was successfully achieved by solvolysis in water/acetone mixtures. The content of water in the solvent markedly influenced the reaction rates. The reactivity of structurally different classes of ferrocenyl ethers was evaluated and in most cases high yields of ferrocenyl alcohols or diols were obtained in a few hours without any additive. Deprotection of less reactive substrates was accelerated in the presence of montmorillonite. The method is simple, environmentally benign and valuable in providing easy access to a variety of ferrocenyl derivatives through the use of the -O-methyl ether protective group.

Mild hydrolytic cleavage of alpha-ferrocenylalkyl-O-methyl ethers

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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

 

Final Thoughts on Chemistry for Ferrocenemethanol

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THE ELECTROPHILIC SUBSTITUTION OF FERROCENE BY PROTONATED CARBONYL COMPOUNDS

The alpha-ferrocenylalkyl carbenium ions are formed from ferrocene and carbonyl compounds in strongly acidic media, in particular mixtures of fluorosulfuric acid and trichloroacetic acid.The alpha-ferrocenylalkyl carbenium ions are scavenged by nucleophiles or bases.The addition of nucleophiles produces the corresponding alpha-substituted ferrocenyl alkanes.Proton abstraction by base from the beta-position leads to the ferrocenylethene derivatives.Such electrophilic substitutions of ferrocene by carbonyl compounds, followed by suitable scavengeing of the alpha-ferrocenylalkyl carbenium ion, form the basis of one-pot syntheses of various ferrocene derivatives.

THE ELECTROPHILIC SUBSTITUTION OF FERROCENE BY PROTONATED CARBONYL COMPOUNDS

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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

 

Can You Really Do Chemisty Experiments About 1,1′-Diacetylferrocene

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Application of 1273-94-5, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.1273-94-5, Name is 1,1′-Diacetylferrocene, molecular formula is C14H6FeO2. In a Article£¬once mentioned of 1273-94-5

A Mononuclear Non-heme Manganese(III)-Aqua Complex as a New Active Oxidant in Hydrogen Atom Transfer Reactions

A mononuclear non-heme Mn(III)-aqua complex, [(dpaq)MnIII(OH2)]2+ (1, dpaq = 2-[bis(pyridin-2-ylmethyl)]amino-N-quinolin-8-yl-acetamidate), is capable of conducting hydrogen atom transfer (HAT) reactions much more efficiently than the corresponding Mn(III)-hydroxo complex, [(dpaq)MnIII(OH)]+ (2); the high reactivity of 1 results from the positive one-electron reduction potential of 1 (Ered vs SCE = 1.03 V), compared to that of 2 (Ered vs SCE = -0.1 V). The HAT mechanism of 1 varies between electron transfer followed by proton transfer and one-step concerted proton-coupled electron transfer, depending on the one-electron oxidation potentials of substrates. To the best of our knowledge, this is the first example showing that metal(III)-aqua complex can be an effective H-atom abstraction reagent.

A Mononuclear Non-heme Manganese(III)-Aqua Complex as a New Active Oxidant in Hydrogen Atom Transfer Reactions

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Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

 

A new application about 1,1′-Ferrocenedicarboxaldehyde

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1271-48-3, Name is 1,1′-Ferrocenedicarboxaldehyde, belongs to iron-catalyst compound, is a common compound. name: 1,1′-FerrocenedicarboxaldehydeIn an article, once mentioned the new application about 1271-48-3.

Metal-directed assembly of polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes

Novel redox-active polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes (10a-c), (11) and (12a-c) are synthesised by reaction of the respective ferrocenyl secondary amines, namely, N,N?-bis(ferrocenemethyl)-1,3-bis(aminomethyl)benzene (4), 1,1?-bis(benzylaminomethyl)ferrocene (8) and 1,1?-bis((ferrocenylmethyl)aminomethyl)ferrocene (9) with carbon disulfide, potassium hydroxide and transition metal (zinc, copper, nickel) acetate in high yields (52-82%) and characterised by spectroscopic and electrochemical techniques. The single-crystal X-ray structure of 10a shows that each zinc atom is in tetrahedral geometry, being bonded to two dithiocarbamate ligands with Zn-S distances 2.32(1)-2.44(1) A.

Metal-directed assembly of polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes

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Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

 

A new application about Ferrocenemethanol

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Chemistry is traditionally divided into organic and inorganic chemistry. Recommanded Product: Ferrocenemethanol, The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent£¬Which mentioned a new discovery about 1273-86-5

Dinuclear platinum(II) complexes containing ferrocenylalkyl-thiolate and -selenolate ligands

Alkylation reactions of [Pt2(mu-S)2(PPh 3)4] with haloalkylferrocenes FcCH2Cl, Fc(CH2)6Br and Fc(CH2)11Br [Fc = (eta5-C5H5)Fe(eta5-C5H4)] gave the cationic mu-thiolate complexes [Pt2(mu-S){mu-S(CH2) nFc}(PPh3)4]+ (n = 1, 6, 11), isolated as PF6 and/or BPh4 salts, and characterised by ESI mass spectrometry, NMR spectroscopy, microelemental analysis, and by an X-ray structure determination on [Pt2(mu-S){mu-SCH2Fc} (PPh 3)4]PF6. The complex contains the typical folded {Pt2(mu-S)2} core with an axial ferrocenylmethylthi-olate ligand. The corresponding selenolate complex [Pt 2(mu-Se){mu-SeCH2Fc}(PPh3) 4]+ was similarly obtained by alkylation of [Pt 2(mu-Se)2(PPh3)4] with FcCH 2Cl, and isolated as PF6 and BPh4 salts. The attempted liberation of FcCH2SH from [Pt2(mu-S){mu- SCH2Fc}(PPh3)4]+ using Na 2S was not successful.

Dinuclear platinum(II) complexes containing ferrocenylalkyl-thiolate and -selenolate ligands

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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

 

Some scientific research about Ferrocenemethanol

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Related Products of 1273-86-5, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.1273-86-5, Name is Ferrocenemethanol, molecular formula is C11H3FeO. In a Review£¬once mentioned of 1273-86-5

Electrochemistry in bicontinuous microemulsions based on control of dynamic solution structures on electrode surfaces

Bicontinuous microemulsions (BMEs, Winsor III), also called middle-phase microemulsions, are low-viscosity, isotropic, thermodynamically stable, and spontaneously formed mixtures of water, oil, and surfactants. They are unique solution media for electrochemistry. Here, we introduce the recent progress in the electrochemistry of BMEs from their fundamental aspects to their practical applications. Electrochemistry using BMEs has two irreplaceable properties: the coexistence of hydrophilic and lipophilic species with high self-diffusion coefficients; and the dynamic deformation of structures at an oil/water/electrode ternary interface, which is easily changed according to the property of the electrode surface. Electrochemical contact with the micro-saline and oil phases in a BME is alternately or simultaneously achieved by controlling the hydrophilicity and lipophilicity of the electrode surfaces. The selective electrochemical analysis of hydrophilic and lipophilic antioxidants in liquid foods without extraction demonstrated as the use of the unique ternary solution structures of BME on solid surfaces.

Electrochemistry in bicontinuous microemulsions based on control of dynamic solution structures on electrode surfaces

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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

 

Brief introduction of Ferrocenemethanol

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Synthetic Route of 1273-86-5, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.1273-86-5, Name is Ferrocenemethanol, molecular formula is C11H3FeO. In a Article£¬once mentioned of 1273-86-5

A disposable Protein A-based immunosensor for flow-injection assay with electrochemical detection

Low-cost disposable immunosensors were produced by covalent binding of Protein A or G on graphite-polystyrene screen-printed electrodes, and they were used in a fully automated flow-injection analysis (FIA) system, allowing the kinetics of IgG binding to Protein A or G to be improved by forced convection. The displacement of rabbit IgG bound to Protein A or G by mouse IgG isotypes (IgG1 or IgG(2a)) was studied. A FIA immunoassay of mouse IgG(2a) was performed at a Protein A-based immunosensor with a good sensibility (down to 0.02mugml-1) and a total assay time of 19min. It was shown that the immunosensor combines the advantages of being reusable for more than 30 assay cycles in flow-injection analysis, and disposable when necessary. Copyright (C) 2000 Elsevier Science B.V.

A disposable Protein A-based immunosensor for flow-injection assay with electrochemical detection

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Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

 

The Absolute Best Science Experiment for 1,1′-Diacetylferrocene

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Electric Literature of 1273-94-5, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.1273-94-5, Name is 1,1′-Diacetylferrocene, molecular formula is C14H6FeO2. In a Article£¬once mentioned of 1273-94-5

Unique Deuterium Exchange Reaction in Certain Substituted Ferrocenes

Deuterium exchange of certain substituted ferrocenes (under very mild basic conditions) occurs in only the substituted cyclopentadienyl-ring in non-statistical pattern; a ?->? (eta5->eta1) rearrangement mechanism is proposed to account for the novel pattern of exchange.

Unique Deuterium Exchange Reaction in Certain Substituted Ferrocenes

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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion

 

Extracurricular laboratory:new discovery of Ferrocenemethanol

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Electric Literature of 1273-86-5, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.1273-86-5, Name is Ferrocenemethanol, molecular formula is C11H3FeO. In a Conference Paper£¬once mentioned of 1273-86-5

Scanning electrochemical microscopy for the investigation of localized degradation processes in coated metals

Scanning electrochemical microscopy has been employed to obtain spatially-resolved information regarding surface topology, water uptake and blister formation at intact coatings, as well as the onset and progress of corrosion reactions within coating defects. Topographical lines and maps as well as chronoamperometric plots were measured during operation in the feedback mode. Next, the release of metal ions at the anodic sites and the consumption of oxygen at the cathodic sites developed in holidays could be monitored during operation in the generator-collector mode. Furthermore, the surface topography of defective coatings was imaged by using the redox competition mode.

Scanning electrochemical microscopy for the investigation of localized degradation processes in coated metals

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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion