Chemistry is traditionally divided into organic and inorganic chemistry. Computed Properties of C12H10FeO2, The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent£¬Which mentioned a new discovery about 1271-48-3
An Enantioselective Oxidative C-H/C-H Cross-Coupling Reaction: Highly Efficient Method to Prepare Planar Chiral Ferrocenes
A Pd-catalyzed, asymmetric oxidative cross-coupling reaction between ferrocenes and heteroarenes is described. The process, which takes place via a twofold C-H bond activation pathway, proceeds with modest to high efficiencies (36-86%) and high levels of regio- and enantioselectivity (95-99% ee). In the reaction, air oxygen serves as a green oxidant and excess amounts of the coupling partners are not required. The process is the first example of a catalytic asymmetric biaryl coupling reaction that occurs via double C-H bond activation. Finally, the generated coupling products can be readily transformed into chiral ligands and catalysts.
An Enantioselective Oxidative C-H/C-H Cross-Coupling Reaction: Highly Efficient Method to Prepare Planar Chiral Ferrocenes
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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion