Related Products of 1271-51-8, Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics.In a document type is Article, and a compound is mentioned, 1271-51-8, Vinylferrocene, introducing its new discovery.
New synthesis of acylferrocene by hydroiminoacylation of the terminal olefin with ferrocenecarboxaldimine and application to polymer-supported acylferrocene
Acylferrocenes were synthesized by hydroiminoacylation of the omega-olefins 1-pentene (3a), vinylferrocene (3b) and but-3-enylferrocene (3c), with the ferrocenecarboxaldimine 2, prepared from ferrocenecarboxaldehyde (1) and 2-amino-3-picoline, under the action of Wilkinson’s catalysts, followed by hydrolysis of the corresponding ketimines (5a, 5b and 5c).This hydroiminoacylation was used to incorporate the ferrocenyl group into phenyl-terminated poly-butadiene (PTPB, consisting of 27percent vinyl and 73percent internal olefin group). 74percent hydroacylation of the vinyl group in 7 wasaccomplished in the first catalytic reaction and in 10 the second hydroacylation completed the conversion of the vinyl group into acylferrocene.
New synthesis of acylferrocene by hydroiminoacylation of the terminal olefin with ferrocenecarboxaldimine and application to polymer-supported acylferrocene
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Related Products of 1271-51-8. In my other articles, you can also check out more blogs about 1271-51-8
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Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion