In heterogeneous catalysis, the catalyst is in a different phase from the reactants. category: iron-catalyst, At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 1271-51-8, name is Vinylferrocene. In an article£¬Which mentioned a new discovery about 1271-51-8
The ?-Bonded Palladium(II) Complex of -(Dimethylaminomethyl)cyclopentadienyl>tetraphenylcyclobutadienecobalt(I)
-(Dimethylaminomethyl)cyclopentadienyl>tetraphenylcyclobutadienecobalt(I) reacts with lithium tetrachloropalladate(II) in the presence of sodium acetate to give an ortho-palladated binuclear complex.The ?-bonded structure of the complex was confirmed by studies of the IR and 1H-NMR spectra and of the reactions with triphenylphosphine, thalium(I) acetylacetonate, and lithium aluminum deuteride.The reactions of the ?-bonded complex with carbon monoxide and olefins have been examined.
The ?-Bonded Palladium(II) Complex of -(Dimethylaminomethyl)cyclopentadienyl>tetraphenylcyclobutadienecobalt(I)
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Reference£º
Iron Catalysis in Organic Synthesis | Chemical Reviews,
Iron Catalysis in Organic Synthesis: A Critical Assessment of What It Takes To Make This Base Metal a Multitasking Champion